Chemical cycles which involve the atmosphere




















On land, carbon is stored in soil as a result of the decomposition of living organisms or the weathering of terrestrial rock and minerals.

This carbon can be leached into the water reservoirs by surface runoff. Deeper underground, on land and at sea, are fossil fuels: the anaerobically-decomposed remains of plants that take millions of years to form. Fossil fuels are considered a non-renewable resource because their use far exceeds their rate of formation.

A non-renewable resource is either regenerated very slowly or not at all. Another way for carbon to enter the atmosphere is from land by the eruption of volcanoes and other geothermal systems.

Carbon sediments from the ocean floor are taken deep within the earth by the process of subduction: the movement of one tectonic plate beneath another. Carbon is released as carbon dioxide when a volcano erupts or from volcanic hydrothermal vents. Carbon dioxide is also added to the atmosphere by the breeding and raising of livestock. This is another example of how human activity indirectly affects biogeochemical cycles in a significant way.

Although much of the debate about the future effects of increasing atmospheric carbon on climate change focuses on fossils fuels, scientists take natural processes, such as volcanoes and respiration, into account as they model and predict the future impact of this increase. Nitrogen, the most abundant gas in the atmosphore, is cycled through the biosphere via the multi-step process of nitrogen fixation, which is carried out by bacteria. Getting nitrogen into the living world is difficult.

Plants and phytoplankton are not equipped to incorporate nitrogen from the atmosphere which exists as tightly-bonded, triple-covalent N 2 , even though this molecule comprises approximately 78 percent of the atmosphere.

Nitrogen enters the living world via free-living and symbiotic bacteria, which incorporate nitrogen into their macromolecules through nitrogen fixation conversion of N 2. Cyanobacteria live in most aquatic ecosystems where sunlight is present; they play a key role in nitrogen fixation. Rhizobium bacteria live symbiotically in the root nodules of legumes such as peas, beans, and peanuts , providing them with the organic nitrogen they need.

Free-living bacteria, such as Azotobacter , are also important nitrogen fixers. Organic nitrogen is especially important to the study of ecosystem dynamics as many ecosystem processes, such as primary production and decomposition, are limited by the available supply of nitrogen.

The nitrogen that enters living systems by nitrogen fixation is successively converted from organic nitrogen back into nitrogen gas by bacteria. This process occurs in three steps in terrestrial systems: ammonification, nitrification, and denitrification. Third, the process of denitrification occurs, whereby bacteria, such as Pseudomonas and Clostridium , convert the nitrates into nitrogen gas, allowing it to re-enter the atmosphere.

Nitrogen fixation : Nitrogen enters the living world from the atmosphere via nitrogen-fixing bacteria. This nitrogen and nitrogenous waste from animals is then processed back into gaseous nitrogen by soil bacteria, which also supply terrestrial food webs with the organic nitrogen they need.

Human activity can release nitrogen into the environment by two primary means: the combustion of fossil fuels, which releases different nitrogen oxides, and the use of artificial fertilizers in agriculture, which are then washed into lakes, streams, and rivers by surface runoff.

A major effect from fertilizer runoff is saltwater and freshwater eutrophication: a process whereby nutrient runoff causes the excess growth of microorganisms, depleting dissolved oxygen levels and killing ecosystem fauna. A similar process occurs in the marine nitrogen cycle, where the ammonification, nitrification, and denitrification processes are performed by marine bacteria. Although the movement of nitrogen from rock directly into living systems has been traditionally seen as insignificant compared with nitrogen fixed from the atmosphere, a recent study showed that this process may indeed be significant and should be included in any study of the global nitrogen cycle.

Phosphorus is an essential element of living things, but, in excess, it can cause damage to ecosystems. Phosphorus is an essential nutrient for living processes. It is a major component of nucleic acid, both DNA and RNA; of phospholipids, the major component of cell membranes; and, as calcium phosphate, makes up the supportive components of our bones.

Phosphorus is often the limiting nutrient necessary for growth in aquatic ecosystems. In addition to phosphate runoff as a result of human activity, natural surface runoff occurs when it is leached from phosphate-containing rock by weathering, thus sending phosphates into rivers, lakes, and the ocean. This rock has its origins in the ocean. Phosphate-containing ocean sediments form primarily from the bodies of ocean organisms and from their excretions.

However, in remote regions, volcanic ash, aerosols, and mineral dust may also be significant phosphate sources. Weathering of rocks and volcanic activity releases phosphate into the soil, water, and air, where it becomes available to terrestrial food webs. Phosphate enters the oceans via surface runoff, groundwater flow, and river flow. Phosphate dissolved in ocean water cycles into marine food webs. Some phosphate from the marine food webs falls to the ocean floor, where it forms sediment. Phosphorus is also reciprocally exchanged between phosphate dissolved in the ocean and marine ecosystems.

The movement of phosphate from the ocean to the land and through the soil is extremely slow, with the average phosphate ion having an oceanic residence time between 20, and , years. Excess phosphorus and nitrogen that enters these ecosystems from fertilizer runoff and from sewage causes excessive growth of microorganisms and depletes the dissolved oxygen, which leads to the death of many ecosystem fauna, such as shellfish and finfish.

This process is responsible for dead zones in lakes and at the mouths of many major rivers. Dead zones : Dead zones occur when phosphorus and nitrogen from fertilizers cause excessive growth of microorganisms, which depletes oxygen, killing flora and fauna.

Worldwide, large dead zones are found in coastal areas of high population density. A dead zone is an area within a freshwater or marine ecosystem where large areas are depleted of their normal flora and fauna.

These zones can be caused by eutrophication, oil spills, dumping of toxic chemicals, and other human activities. The number of dead zones has been increasing for several years; more than of these zones were present as of One of the worst dead zones is off the coast of the United States in the Gulf of Mexico, where fertilizer runoff from the Mississippi River basin has created a dead zone of over 8, square miles.

Phosphate and nitrate runoff from fertilizers also negatively affect several lake and bay ecosystems, including the Chesapeake Bay in the eastern United States, which was one of the first ecosystems to have identified dead zones.

But since the start of the Industrial Revolution about years ago humans have burned so much fuel and released so much carbon dioxide into the air that global climate has risen over one degree Fahrenheit.

The atmosphere has not held this much carbon for at least , years according to data from ice cores. The recent increase in amounts of greenhouse gases such as carbon dioxide is having a significant impact on the warming of our planet.

Carbon moves through our planet over longer time scales as well. For example, over millions of years weathering of rocks on land can add carbon to surface water which eventually runs off to the ocean. Over long time scales, carbon is removed from seawater when the shells and bones of marine animals and plankton collect on the sea floor.

These shells and bones are made of limestone, which contains carbon. When they are deposited on the sea floor, carbon is stored from the rest of the carbon cycle for some amount of time. The amount of limestone deposited in the ocean depends somewhat on the amount of warm, tropical, shallow oceans on the planet because this is where prolific limestone-producing organisms such as corals live.

The carbon can be released back to the atmosphere if the limestone melts or is metamorphosed in a subduction zone. Nitrogen is an element that is found in both the living portion of our planet and the inorganic parts of the Earth system. Nitrogen moves slowly through the cycle and is stored in reservoirs such as the atmosphere, living organisms, soils, and oceans along the way. Most of the nitrogen on Earth is in the atmosphere. All plants and animals need nitrogen to make amino acids, proteins and DNA, but the nitrogen in the atmosphere is not in a form that they can use.

The molecules of nitrogen in the atmosphere can become usable for living things when they are broken apart during lightning strikes or fires, by certain types of bacteria, or by bacteria associated with legume plants. Other plants get the nitrogen they need from the soils or water in which they live mostly in the form of inorganic nitrate NO Nitrogen is a limiting factor for plant growth. Animals get the nitrogen they need by consuming plants or other animals that contain organic molecules composed partially of nitrogen.

When organisms die, their bodies decompose bringing the nitrogen into soil on land or into the oceans. The ammonium salts are absorbed onto clay in the soil and then chemically altered by bacteria into nitrite NO2- and then nitrate NO Nitrate is the form commonly used by plants. It is easily dissolved in water and leached from the soil system. Dissolved nitrate can be returned to the atmosphere by certain bacteria through a process called denitrification. Certain actions of humans are causing changes to the nitrogen cycle and the amount of nitrogen that is stored in reservoirs.

Organisms are connected in many ways, even among different ecosystems. A good example of this connection is the exchange of carbon between heterotrophs and autotrophs by way of atmospheric carbon dioxide. Carbon dioxide CO 2 is the basic building block that autotrophs use to build high-energy compounds such as glucose. The energy harnessed from the Sun is used by these organisms to form the covalent bonds that link carbon atoms together. These chemical bonds store this energy for later use in the process of respiration.

Most terrestrial autotrophs obtain their carbon dioxide directly from the atmosphere, while marine autotrophs acquire it in the dissolved form bicarbonate, HCO 3 —. Carbon is passed from producers to higher trophic levels through consumption. Those organic compounds can then be passed to higher trophic levels, such as humans, when we eat the cow. At each level, however, organisms are performing respiration , a process in which organic molecules are broken down to release energy.

As these organic molecules are broken down, carbon is removed from food molecules to form CO 2 , a gas that enters the atmosphere. Thus, CO 2 is a byproduct of respiration. Recall that CO 2 is consumed by producers during photosynthesis to make organic molecules. As these molecules are broken down during respiration, the carbon once again enters the atmosphere as CO 2.

Carbon exchange like this potentially connects all organisms on Earth. Think about this: the carbon in your DNA was once part of plant; millions of years ago perhaps it was part of dinosaur. The movement of carbon through land, water, and air is complex, and, in many cases, it occurs much more slowly than the movement between organisms. As stated, the atmosphere is a major reservoir of carbon in the form of carbon dioxide that is essential to the process of photosynthesis.

The level of carbon dioxide in the atmosphere is greatly influenced by the reservoir of carbon in the oceans. The exchange of carbon between the atmosphere and water reservoirs influences how much carbon is found in each. Carbon dioxide CO 2 from the atmosphere dissolves in water and reacts with water molecules to form ionic compounds. Some of these ions combine with calcium ions in the seawater to form calcium carbonate CaCO 3 , a major component of the shells of marine organisms.

These organisms eventually die and their shells form sediments on the ocean floor. Over geologic time, the calcium carbonate forms limestone, which comprises the largest carbon reservoir on Earth. Deeper underground are fossil fuels, the anaerobically decomposed remains of plants and algae that lived millions of years ago.

Fossil fuels are considered a non-renewable resource because their use far exceeds their rate of formation. A non-renewable resource is either regenerated very slowly or not at all.

Another way for carbon to enter the atmosphere is from land including land beneath the surface of the ocean by the eruption of volcanoes and other geothermal systems.

Carbon sediments from the ocean floor are taken deep within Earth by the process of subduction : the movement of one tectonic plate beneath another. Carbon is released as carbon dioxide when a volcano erupts or from volcanic hydrothermal vents. Getting nitrogen into living organisms is difficult. Plants and phytoplankton are not equipped to incorporate nitrogen from the atmosphere where it exists as tightly bonded, triple covalent N 2 even though this molecule comprises approximately 78 percent of the atmosphere.

Nitrogen enters the living world through free-living and symbiotic bacteria, which incorporate nitrogen into their organic molecules through specialized biochemical processes. At this point, the nitrogen-containing molecules are used by plants and other producers to make organic molecules such as DNA and proteins.

This nitrogen is now available to consumers. Organic nitrogen is especially important to the study of ecosystem dynamics because many ecosystem processes, such as primary production, are limited by the available supply of nitrogen. As shown in Figure 4 below, the nitrogen that enters living systems is eventually converted from organic nitrogen back into nitrogen gas by bacteria Figure 4. The process of denitrification is when bacteria convert the nitrates into nitrogen gas, thus allowing it to re-enter the atmosphere.

Human activity can alter the nitrogen cycle by two primary means: the combustion of fossil fuels, which releases different nitrogen oxides, and by the use of artificial fertilizers which contain nitrogen and phosphorus compounds in agriculture, which are then washed into lakes, streams, and rivers by surface runoff.

A major effect from fertilizer runoff is saltwater and freshwater eutrophication , a process whereby nutrient runoff causes the overgrowth of algae, the depletion of oxygen, and death of aquatic fauna. In marine ecosystems, nitrogen compounds created by bacteria, or through decomposition, collects in ocean floor sediments.

Although the movement of nitrogen from rock directly into living systems has been traditionally seen as insignificant compared with nitrogen fixed from the atmosphere, a recent study showed that this process may indeed be significant and should be included in any study of the global nitrogen cycle. Phosphorus is an essential nutrient for living processes.

Human use of water can transform the water cycle through irrigation or the construction of dams, for example. Ecosystem s - Nutrients. This summary is free and ad-free, as is all of our content. You can help us remain free and independant as well as to develop new ways to communicate science by becoming a Patron! Related words:. To read about this term in context:. Translation s :.



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